| Czech Open Women | 2019/08/21 09:10 | Karoline Mischek v Maria Xiao | L | 0-4 |
| Qatar Open kvinner | 2017/09/14 11:30 | Karoline Mischek v Maria Xiao | L | 1-3 |
| WTT Contender Amman - Kvinner - Kval 2023 | 2023/02/07 15:40 | Amelie Solja v Karoline Mischek | W | 1-3 |
| WTT Contender Amman - Kvinner - Kval 2023 | 2023/02/06 14:35 | Karoline Mischek v Ece Harac | W | 3-1 |
| WTT Contender Doha - Kvinner - Kval | 2023/01/15 12:35 | Hoi Man Karen Lee v Karoline Mischek | L | 3-1 |
| WTT Feeder Düsseldorf - Kvinner | 2022/11/22 17:15 | Leili Mostafavi v Karoline Mischek | L | 3-1 |
| WTT Contender Novo Gorica Women | 2022/11/01 09:05 | Karoline Mischek v Camille Lutz | L | 1-3 |
| WTT Feeder Olomouc - Kvinner | 2022/08/26 14:15 | Sreeja Akula v Karoline Mischek | L | 4-1 |
| WTT Feeder Olomouc - Kvinner | 2022/08/25 12:35 | Adriana Illasova v Karoline Mischek | W | 0-4 |
| EM - Kvinner | 2022/08/18 08:00 | Karoline Mischek v Sabina Surjan | L | 0-4 |
| WTT Contender Amman - Kvinner - Kval 2023 | 2023/02/07 15:40 | Ana Tofant v Maria Xiao | W | 0-3 |
| Champions League - Kvinner | 2023/01/25 18:00 | Maria Xiao v Camille Lutz | W | 3-0 |
| Champions League - Kvinner | 2023/01/25 17:10 | Maria Xiao v Olga Mikhaylova | W | 3-1 |
| European Champions League - Women | 2023/01/23 20:25 | Sarah De Nutte v Maria Xiao | W | 1-3 |
| European Champions League - Women | 2023/01/23 18:45 | Camille Lutz v Maria Xiao | W | 2-3 |
| WTT Contender Doha Women | 2023/01/18 13:00 | Yu-Jhun Li v Maria Xiao | L | 3-1 |
| WTT Contender Doha - Kvinner - Kval | 2023/01/17 11:00 | Christina Kallberg v Maria Xiao | W | 1-3 |
| WTT Contender Doha - Kvinner - Kval | 2023/01/16 16:05 | Lin Qian Ser v Maria Xiao | W | 0-3 |